We report a detailed study of the decomposition of a nerve-agent simulant on metal-organic frameworks (MOFs) using advanced synchrotron-based methods. J. Am. Chem. Soc. 2017, 139, 599−602
Full PublicationThe decomposition of Sarin has been elucidated on Zr-based UiO-66 and MOF-808 metal organic frameworks (MOFs) using electronic structure calculations. J. Phys. Chem. C 2016, 120, 29312−29323
Full PublicationAmbient pressure in situ synchrotron-based spectroscopic techniques have been correlated to illuminate atomic-level details of bond breaking and formation during the hydrolysis of a CWA simulant over a polyoxometalate catalyst. Scientific Reports | 7: 773
Full PublicationHydrocarbon diffusion and binding within porous molecular networks are critical to catalysis, separations, and purification technologies. Fundamental insight into butane uptake and mobility within MOFs, has been gained through in situ infrared spectroscopy. J. Phys. Chem. C 2017.
Full PublicationWe are a multidisciplinary group of scientists from around the country focused on building new catalysts for the decomposition of toxic compounds.
Develop a detailed understanding of interfacial reaction mechanisms at next-generation catalysts that guides the discovery of new materials for soldier and civilian protection.